12-Chloro-6-cyclohexyl-5,6,7,12-tetrahydrodibenzo[c,f][1,5]azastibocine
نویسندگان
چکیده
In the title organometallic complex, [Sb(C(20)H(23)N)Cl], the central anti-mony-containing part of the complex exhibits a pseudo-trigonal-bipyramidal geometry, where two C atoms and a lone electron pair of the Sb atom exist at the equatorial positions, while the N and Cl atoms are located at the apical positions, and a transannular inter-action exists between the Sb and N atoms on 1,5-aza-stibocine. Inter-molecular C-H⋯Cl hydrogen bonds are also observed.
منابع مشابه
6-(1-Methylethyl)-12-phenyl-5,6,7,12-tetrahydrodibenz[c,f][1,5]azasilocine
The title compound, C(23)H(25)NSi, has an eight-membered silicon-containing heterocyclic ring with an intra-molecular N⋯Si close contact, the transannular distance of which is 2.6294 (18) Å. The resulting geometry about the Si atom is distorted trigonal-bypyramidal, with the N and H atoms occupying apical sites. The dihedral angle between the aromatic rings fused to the eight-membered ring is 6...
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